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Vanadium(V) oxytriisopropoxide
404926
DOWNLOAD MSDS (PDF)Synonym: Triisopropoxyvanadium(V) oxide, Vanadium(V) trisisopropoxide oxide
CAS Number: 5588-84-1
Linear Formula: OV(OCH(CH3)2)3
Molecular Weight: 244.20
EC Number: 226-997-4
MDL number: MFCD00015017
PubChem Substance ID: 24865281
Properties
| Related Categories | Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Vanadium |
| form | liquid |
| refractive index | n |
| bp | 80-82 °C/2 mmHg(lit.) |
| density | 1.035 g/mL at 25 °C(lit.) |
Description
Packaging
1, 10 g in glass btl
Application
Building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis.1
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Price and Availability
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Documents
Certificate of Analysis
| FT-IR Condensed Phase |  |
| FT-IR Raman | |
| Structure Search |  |
| Pressure-Temperature Nomograph |  |
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Safety Information
| Symbol |   GHS02, GHS07 |
| Signal word | Warning |
| Hazard statements | H226-H315-H319-H335 |
| Precautionary statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 16-26-27 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| Flash Point(F) | 113 °F |
| Flash Point(C) | 45 °C |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
CBHA Ligands
Yamamoto and his group developed a new type of ligands based on the C2-symmetric chiral bishydroxamic acid (CBHA). These bidentate ligands have pendant "arms" that can be substituted with a variety o...
Dr. Daniel Weibel
Chemfiles Volume 10 Article 1
Keywords: Asymmetric synthesis, Building blocks, Catalog, Epoxidations, Jacobsen Epoxidation, Ligands, Oxidations, Sharpless Epoxidation
References
1. Jiang, F. et al. Inorg. Chem. 37, 5439, (1998) Abstract
Beil. 1,IV,1242
FT-IR 2 (3), 4493:C / Structure Index 1, 484:D:8
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